The Knowledge passive works very similarly to Catchup.
On a technical level, it just adds 0.05 to 0.15 to the same Exp multiplier.
It doesn't multiply with Catchup, and it also doesn't apply very often, just as Catchup— only applying on battle-related Exp on your main team.

Many people have thusly found the Passive to be completely useless, and while I do agree to a certain extent, the passive is certainly difficult to use:

I don't believe most players give it it's due consideration. It can actually be worth the effort if you're optimising your team for Exp-effectiveness, as most players are.

The Desmos link I've added to NeonUtil Global above gives you your Battle exp. Feel free to do the calculations yourself, whether the passive is worth your time! :heart: I hope I'm spreading my enthusiasm for math.

I won't be talking about Knowledge in Weapons & Passives, I feel like these paragraphs here are sufficient.